be an antidote to vs invalidate

be an antidote to

invalidate

verb
  • To make invalid. Especially applied to contract law. 

  • To make or declare (an argument, statement, or theory) unsound or erroneous; disprove. 

  • To render invalid; discredit. 

How often have the words be an antidote to and invalidate occurred in a corpus of books? (source: Google Ngram Viewer )