deputize vs substitute

deputize

verb
  • To act as a substitute for a person in their role or office 

  • to officially empower and authorize (someone) to act as a substitute in one's role or office 

  • To officially empower, authorize, pronounce, and establish (someone) to be a deputy. 

substitute

verb
  • To serve as a replacement (for someone or something). 

  • To remove (a player) from the field of play and bring on another in his place. 

  • To use in place of something else, with the same function. 

  • To use X in place of Y. 

  • To use Y in place of X; to replace X with Y. 

noun
  • A player who is available to replace another if the need arises, and who may or may not actually do so. 

  • A replacement or stand-in for something that achieves a similar result or purpose. 

  • One who enlists for military service in the place of a conscript. 

How often have the words deputize and substitute occurred in a corpus of books? (source: Google Ngram Viewer )