enroll vs secede

enroll

verb
  • To enlist oneself (in something) or become a member (of something) 

  • To enter (a name, etc.) in a register, roll or list 

  • To enlist (someone) or make (someone) a member of 

secede

verb
  • To split from or to withdraw from membership of a political union, an alliance or an organisation. 

  • To split or to withdraw one or more constituent entities from membership of a political union, an alliance or an organisation. 

How often have the words enroll and secede occurred in a corpus of books? (source: Google Ngram Viewer )