materia medica vs recreational pharmaceutical

materia medica

noun
  • Synonym of medicine: the substances so used, particularly traditional cures prepared from animals and plants such as herbal medicines but inclusive of early drugs. 

  • Synonym of pharmacology, particularly its development in early modern Europe. 

recreational pharmaceutical

noun
  • A medication or similar controlled substance which is consumed outside the context of normal medical treatment for the sole purpose of inducing pleasant sensations, mental reverie, or a state of intoxication. 

How often have the words materia medica and recreational pharmaceutical occurred in a corpus of books? (source: Google Ngram Viewer )