invalid vs nullified

invalid

adj
  • Intended for use by an invalid. 

  • Not valid; not true, correct, acceptable or appropriate. 

  • Suffering from disability or illness. 

verb
  • To make invalid or affect with disease. 

  • To exempt from (often military) duty because of injury or ill health. 

nullified

adj
  • That has been declared null 

  • Whose value has been set to null 

How often have the words invalid and nullified occurred in a corpus of books? (source: Google Ngram Viewer )