chagrin vs perturbation

chagrin

noun
  • Distress of mind caused by a failure of aims or plans, want of appreciation, mistakes etc; vexation or mortification. 

  • A type of leather or skin with a rough surface. 

verb
  • To bother or vex; to mortify. 

perturbation

noun
  • Agitation; the state of being perturbed 

  • Variation in an orbit due to the influence of external bodies 

  • A small change in a physical system, or more broadly any definable system (such as a biological or economic system) 

How often have the words chagrin and perturbation occurred in a corpus of books? (source: Google Ngram Viewer )