sign on vs volunteer

sign on

verb
  • To commit oneself, as to a project, a goal, an organization, a cause. 

  • To begin broadcasting a radio or television signal, usually at the beginning of a broadcasting day and after being off the air for several hours. 

  • To join something, after signing. 

  • To apply to receive unemployment benefits. 

  • To log on; to start using a computer, radio, etc., or to start talking. 

noun
  • The time of day when a radio or television station begins broadcasting, usually after being off the air for several hours. 

volunteer

verb
  • To enlist oneself as a volunteer. 

  • To offer, usually unprompted. 

  • To grow without human sowing or intentional cultivation. 

  • To offer the services of (someone else) to do something. 

  • To do or offer to do something voluntarily. 

noun
  • A plant that grows spontaneously, without being cultivated on purpose; see volunteer plant in Wikipedia. 

  • A voluntary member of the organized militia of a country, as distinguished from a regular or member of the standing army. 

  • One who enters into military service voluntarily (but who, when in service, is subject to discipline and regulations like other soldiers), as opposed to a conscript. 

  • A native or resident of the American state of Tennessee. 

  • One who enters into, or offers themself for, any service of their own free will, especially when done without pay. 

  • A person who acts out of their own will without a legal obligation, such as a donor. 

How often have the words sign on and volunteer occurred in a corpus of books? (source: Google Ngram Viewer )