unbound vs untied

unbound

adj
  • Not bound; not tied up. 

  • Without a binding. 

  • Lying beyond the proton or neutron drip line; having a negative particle separation energy; capable of decaying by the spontaneous exothermic emission of one or more nucleons. 

untied

adj
  • Not tied; undone 

How often have the words unbound and untied occurred in a corpus of books? (source: Google Ngram Viewer )