neutralize vs validate

neutralize

verb
  • To make even, inactive or ineffective. 

  • To kill. 

  • To make (a territory, etc.) politically neutral. 

  • To make (an acidic or alkaline substance) chemically neutral. 

validate

verb
  • To check or prove the validity of; verify. 

  • To have its validity successfully proven. 

  • To render valid. 

How often have the words neutralize and validate occurred in a corpus of books? (source: Google Ngram Viewer )